桐柏造山带榴辉岩早古生代高压变质作用的发现     

李乐倩  张宏福 《岩石学报》2021,37(12):3575-3590

桐柏造山带是连接秦岭造山带和红安-大别造山带的枢纽,一直被认为是三叠纪变质带。本文通过对其南部高压榴辉岩带内榴辉岩和白云母石英片岩的全岩化学、锆石U-Pb年代学和Lu-Hf同位素地球化学研究,首次确定该地区的榴辉岩存在早古生代变质作用。榴辉岩主要由石榴石、绿辉石和角闪石组成,含少量多硅白云母、石英和金红石等。榴辉岩中锆石的²⁰⁶Pb/²³⁸U加权平均年龄为452±5Ma,这些锆石具有低Th/U比值、低¹⁷⁶Lu/¹⁷⁷Hf比值,并具有平坦的HREE配分型式和无Eu负异常的特征,即为典型榴辉岩相的变质锆石。因此,452Ma代表该榴辉岩的变质时间。此外,白云母石英片岩中的锆石SIMS定年也获得450±93Ma的下交点年龄,证明白云母石英片岩与榴辉岩皆记录了早古生代的变质事件。榴辉岩的主微量元素及锆石Hf同位素特征反映榴辉岩原岩形成于板内环境,并且在侵位过程中遭到古老地壳物质的混染。结合桐柏造山带内不同岩石类型中早古生代的变质年龄,表明早古生代的变质作用在桐柏造山带内是普遍存在的。同时,桐柏造山带早古生代榴辉岩相变质事件的发现,进一步说明其经历了从古生代到中生代多阶段的构造演化。  相似文献   

内蒙古中东部上侏罗统满克头鄂博组划分及时代          下载免费PDF全文

张永清 《地球科学》2021,46(1):162-171

内蒙古自治区中东部满克头鄂博组以流纹质火山碎屑岩为主夹山间湖盆相陆相碎屑岩及少量流纹岩或英安岩.沉积岩中产叶肢介Magumbonia paramecia,Nestoria reticulate,N.xishunjingensis,N.cf.pissoui,Lioestheria sp.;双壳类Ferganoconcha curta,F.subcentralis,F.elongate;植物:Ginkgoites sp.,Cladophlebis sp.,Lycopodites sp.,Baiera gracilis,Phoenicopsis sp.化石.岩石化学SiO₂71.47%~75.96%,Ai₂O₃12.50%~14.18%,K₂O 3.84%~4.98%,Na₂O 3.22%~4.14%,ALK 7.84%~9.12%,K₂O>Na₂O,显示高硅高碱特征;微量元素组成上以富集Rb、K、Th、U、La和LREE,亏损Ba、Nb、Sr、P和Ti为特征;稀土元素ΣREE=47.116×10-6~176.78×10-6,轻重稀土分溜明显,分溜系数（La/Yb）_N为4.79~25.56,δEu为0.05~0.61,为中等铕负异常.4个样品在logδ-logτ图解上全部落入造山带山花岗岩区、Rb-Y+Nb图解上落在火山弧花岗岩区、Nb-Y图解上全部落入火山弧花岗岩同碰撞花岗岩区;在阿巴嘎旗-扎鲁特旗-巴林右旗一带采集了4个锆石LA-MC-IC-MS同位素,年龄值分别为138.89±0.93 Ma、137.70±1.40 Ma、147.70±1.20 Ma和137.27±0.96 Ma,将满克头鄂博组的时代置于晚侏罗世-早白垩世.   相似文献   

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples     

Wei‐Xin Lv  Hao‐Ming Yin  Meng‐Shu Liu  Fang Huang  Hui‐Min Yu 《Geostandards and Geoanalytical Research》2021,45(1):245-256

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.  相似文献   

冀东峪耳崖金矿区闪长岩脉地球化学特征及其地质意义     

杨爱雪  孙德有  侯雪刚  王久良  张继林  李临位 《吉林大学学报(地球科学版)》2021,51(2):416-428

冀东地区位于华北板块北缘燕山造山带东部,矿产资源丰富,是中国金矿的主要产地之一,尤其是热液型金矿。峪耳崖金矿床是冀东众多热液型金矿床的典型代表,金矿主体赋存于侏罗纪峪耳崖花岗岩体内,少部分赋存于侵入花岗岩体的侏罗纪闪长岩脉中。闪长岩脉元素地球化学分析显示：w（SiO₂）为51.99%~61.88%、Mg^#值为0.37~0.64,w（Na₂O+K₂O）为5.07%~8.89%,A/NK为1.37~2.26,A/CNK为0.73~0.96,属准铝质高钾钙碱性系列;富集轻稀土元素和大离子亲石元素Rb、Ba、K、Sr,亏损重稀土元素和高场强元素Nb、Ta、Ti。锆石原位Hf同位素测试表明,ε_Hf（t）为负值,介于-16.5~-6.5之间。综合研究认为：峪耳崖金矿区侏罗纪闪长岩浆源于俯冲流体交代的富集岩石圈地幔,岩浆上侵过程中受到华北板块古老下地壳物质的有限混染;成矿期闪长岩浆为金成矿提供了部分物质来源;峪耳崖金矿区闪长岩脉形成于古太平洋板块向欧亚大陆俯冲的动力学背景。  相似文献   

辽东石庙沟岩体岩石地球化学特征、锆石U-Pb年龄、Hf同位素及其地质意义     

王世成  杨仲杰  杨菊  张璟  孙守亮  刘长纯 《吉林大学学报(地球科学版)》2021,51(2):429-441

辽东石庙沟地区位于华北陆块东部的辽吉造山/活动带上,该带经历了十分复杂的构造演化过程,记录了多期岩浆-构造-变质事件。石庙沟岩体为花岗斑岩,富SiO₂、Na₂O和K₂O,贫CaO、MgO及Al₂O₃,亏损高场强元素（Nb、Ti、Ta、P）,富集大离子亲石元素（K、Rb、Ba、U）,A/CNK值大于1,REE配分曲线呈"海鸥"式分布,以具有显著的负Eu异常为特征,高Ga/Al值,与典型A型花岗岩特征一致。花岗斑岩中锆石的LA-ICP-MS U-Pb测年结果表明其成岩年龄为（123.0±1.6）Ma,为早白垩世。锆石Hf同位素分析表明,ε_Hf（t）值均为负值,介于-15.72~-12.85之间,平均值为-14.14,二阶段模式年龄（T_DM2）在2 164~1 989 Ma之间,平均为2 067 Ma,反映源岩以大陆壳成分为主。结合花岗斑岩高SiO₂,低Mg、Co、Cr、Ni,且富集LREE和LILE,亏损HFSE等特征,表明早白垩世花岗斑岩岩浆应为大陆地壳物质熔融的产物。根据年代学和岩石地球化学研究认为,早白垩世花岗斑岩是古太平洋板块向欧亚大陆板块俯冲所形成的活动大陆边缘弧花岗岩。研究区早白垩世花岗斑岩的形成主要受太平洋构造域的影响,形成环境受板块俯冲造山后伸展作用和下地壳拆沉作用的联合制约,是辽东地区岩石圈减薄的直接证据。  相似文献   

Integration of zircon and apatite U–Pb geochronology and geochemical mapping of the Wude basalts(Emeishan large igneous province):A tool for a better understanding of the tectonothermal and geodynamic evolution of the Emeishan LIP     

Jia-Nan Fu  Franco Pirajno  Fan Yang  Espine Shivute  Yi-Zhan Sun  Ning Ai  Kun-Feng Qiu 《地学前缘(英文版)》2021,12(2):573-585

Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadε_Hf(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.  相似文献   

大陆碰撞造山带榴辉岩相的熔体活动:来自南阿尔金基性麻粒岩中长英质脉体的证据     

郭晶  李云帅  张建新 《地质学报》2021,95(3):723-736

本文通过对南阿尔金巴什瓦克基性麻粒岩中长英质脉体的岩相学、锆石U-Pb年代学、Lu-Hf同位素及全岩主微量地球化学的综合研究,首次限定了该区基性麻粒岩中长英质脉体的形成时代为491±2 Ma (MSWD=0.91),此年龄与寄主麻粒岩高压—超高温阶段(榴辉岩相)的变质时代在误差范围内近一致,表明长英质脉体形成于榴辉岩相的变质阶段。由于长英质脉体中锆石明显不同于寄主基性麻粒岩中变质锆石的形态特征,基本排除了长英质脉体中的锆石为捕获锆石的可能性。此外,该长英质脉体中的锆石具有少量的长石、石英包裹体和较低的Th/U比值(0.05-0.41),锆石稀土元素配分模式图显示其具有重稀土富集和Eu负异常的特征,这些证据表明长英质脉体中的锆石可能结晶于变质熔体之中。长英质脉体的全岩地球化学特征显示其该脉体具有相对较低的K2O值,基本上排除了其来源于围岩长英质麻粒岩的可能,而且这些锆石的Hf同位素特征与寄主岩石的锆石Hf同位素特征具有相似性,表明形成长英质脉体的熔体为内部来源。结合全岩地球化学特征,推测其可能为基性麻粒岩发生部分熔融所致。  相似文献   

Petrogenesis of mafic microgranular enclaves (MMEs) in the oligocene-miocene granitoid plutons from northwest Anatolia,Turkey     

《Chemie der Erde / Geochemistry》2021,81(2):125713

Mafic microgranular enclaves (MMEs) in host granitoids can provide important constraints on the deep magmatic processes. The Oligocene-Miocene granitoid plutons of the NW Anatolia contain abundant MMEs. This paper presents new hornblende Ar-Ar ages and whole-rock chemical and Sr-Nd isotope data of the MMEs from these granitic rocks. Petrographically, the MMEs are finer-grained than their host granites and contain the same minerals as their host rocks (amphibole + plagioclase + biotite + quartz + K-feldspar), but in different proportions. The Ar-Ar ages of the MMEs range from 27.9 ± 0.09 Ma to 19.3 ± 0.01 Ma and are within error of their respective host granitoids. The MMEs are metaluminous and calc-alkaline, similar to I-type granites. The Sr-Nd isotopes of MMEs are 0.7057 to 0.7101 for ⁸⁷Sr/⁸⁶Sr and 0.5123 to 0.5125 for ¹⁴³Nd/¹⁴⁴Nd, and are similar to their respective host granitoids. These lithological, petrochemical and isotopic characteristics suggest that the MMEs in this present study represent chilled early formed cogenetic hydrous magmas produced during a period of post-collisional lithospheric extension in NW Anatolia. The parental magma for MMEs and host granitoids might be derived from partial melting of underplated mafic materials in a normally thickened lower crust in a post-collisional extensional environment beneath the NW Anatolia. Delamination or convective removal of lithospheric mantle generated asthenospheric upwelling, providing heat and magma to induce hydrous re-melting of underplated mafic materials in the lower crust.  相似文献   

钙同位素地球化学研究新进展及其在碳酸岩-共生硅酸盐研究中的应用     

向蜜  龚迎莉  刘涛  田世洪 《地质学报》2021,95(12):3937-3960

作为"非传统稳定同位素"家族成员,钙同位素正受到国际地学界日益广泛的关注.钙是主要的造岩元素,也是生物必需的元素.钙在地球各圈层广泛分布,研究钙同位素的地球化学行为将有助于提高我们对各种生物过程和地质过程的认识.钙同位素测定主要采用热电离质谱仪(TIMS)和多接收电感耦合等离子体质谱仪(MC-ICP-MS),分别表示为δ44/40 Ca和δ44/42Ca.目前自然界可观测到的δ44/40Ca变化范围为-2.0‰～6.75‰,约8.7‰.本文系统介绍了近年来钙同位素分析中样品溶解、化学分离、质谱测定以及高温地质过程中的钙同位素分馏及其地质应用等方面的研究成果,尤其对钙同位素在碳酸岩-共生硅酸盐岩研究中的意义、钙同位素组成以及取得的主要认识作了较为全面的介绍.阐述了放射成因40 Ca、部分熔融作用/分离结晶作用、地壳同化作用、古俯冲碳酸盐循环、热液蚀变作用、岩浆起源深度等对碳酸岩、硅酸盐岩的钙同位素组成造成的影响.最后,通过系统对比碳酸岩-共生硅酸盐岩的锂、镁、钙同位素研究成果,认为应该开展多元同位素体系的联合示踪.由于不同同位素体系存在相似性和差异性,而多元同位索体系相结合能有效地加强优势互补,将是同位素地球化学研究发展的一种必然趋势.  相似文献   

尼泊尔低喜马拉雅推覆带油源对比及油气成藏     

杨平  谭富文  施美凤  王正和  李忠雄  占王忠  Sudhir RAJAURE  Ganesh N.TRIPATHI 《地质学报》2021,95(11):3426-3441

尼泊尔低喜马拉雅推覆带油气苗来源不清极大地影响了该区油气勘探.在地质-地球物理综合调查的基础上,利用油气地球化学、碳同位素及生烃史模拟对尼泊尔代莱克地区油源和成藏过程进行了研究.结果表明:①尼泊尔代莱克地区油苗产于Padukasthan断裂,可分两期,第一期呈含油断层泥产出,氯仿沥青"A"为149～231 μg/g,RR.为0.81％,氯仿沥青"A"的δ13C相对较重(-26.24‰～-27.10‰),族组分具有正碳同位素序列,发黄绿色荧光,为典型的低熟煤成油,第二期呈液态油产出并遭受微生物降解,金刚烷IMD指数为0.33～0.45,R.为1.24％～1.53％,3,4-DMD含量46％～47％,全油δ13C为-29.50‰～-29.45‰,族组分碳同位素趋于一致,发蓝色荧光,为海相成因高熟油;②第一期油来源于Surkhet群的Melpani组和Gondwana群煤系烃源岩,为Ⅲ型有机质低熟阶段的产物,第二期来源于Surkhet群的Swat组浅海陆棚相黑色页岩,为Ⅱ1型有机质生油高峰的产物,两期油与Lakharpata群过成熟黑色泥岩和Siwalik群未熟泥岩没有亲缘关系;③尼泊尔低喜马拉雅推覆带具有"多源多期、推覆增熟、砂体控储、披覆控聚"的油气成藏模式,油气成藏过程可划分为沉积浅埋、构造圈闭形成、深埋油藏形成、气藏形成和晚期改造定型5个演化阶段;④尼泊尔低喜马拉雅推覆有利于Gondwana群、Surkhet群深埋增温、持续快速生烃和晚期成藏,对比邻区巴基斯坦的含油气盆地,尼泊尔低喜马拉雅推覆带及相邻类似地区具备良好的油气成藏条件.  相似文献